Kinetics of pressure induced structural changes in super- or near-critical CO2-microemulsions.

نویسندگان

  • Alexander Müller
  • Yvonne Pütz
  • Roland Oberhoffer
  • Nils Becker
  • Reinhard Strey
  • Albrecht Wiedenmann
  • Thomas Sottmann
چکیده

CO2-microemulsions show strong pressure dependent properties. Using time-resolved SANS to investigate the kinetics of structural changes upon periodic pressure jumps of adjustable amplitude, we found that the compression-induced formation of cylinders occurs on a timescale of one second, whereas the expansion-induced disintegration into CO2 swollen spherical micelles is much faster.

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عنوان ژورنال:
  • Physical chemistry chemical physics : PCCP

دوره 16 34  شماره 

صفحات  -

تاریخ انتشار 2014